Evidence
Chem Rec. 2023 Jul 7:e202300148. doi: 10.1002/tcr.202300148. Online ahead of print.
ABSTRACT
Heterogeneous noble metal catalysts exhibit various functions. Although their redox functions have been extensively studied, we focused on their soft Lewis acid functions. Supported Au, Pt, and Pd catalysts electrophilically attack the π-electrons of soft bases such as alkynes, alkenes, and aromatic compounds to perform addition and substitution reactions. Hydroamination, intramolecular cyclization of alkynyl carboxylic acids, isomerization of allylic esters, vinyl exchange reactions, Wacker oxidation, and oxidative homocoupling of aromatics are introduced based on a discussion of the active species and reaction mechanisms. Furthermore, the adsorption of sulfur compounds, which are soft bases, onto the supported AuNPs is discussed. The adsorption and removal of 1,3-dimethyltrisulfane (DMTS), which is the compound responsible for the stale odor of “hine-ka” in alcoholic beverages, particularly Japanese sake, is described.
PMID:37417711 | DOI:10.1002/tcr.202300148
Add to Google Keep
Estimated reading time: 3 minute(s)
Latest: Psychiatryai.com #RAISR4D
Real-Time Evidence Search [Psychiatry]
Supported Noble Metal Catalysts and Adsorbents with Soft Lewis Acid Functions
🌐 90 Days
VR Related Evidence Matrix
- A novel activation function based on DNA enzyme-free hybridization reaction and its implementation on nonlinear molecular learning systems
- Exploration of carbonyl compounds in red-fleshed kiwifruit wine and perceptual interactions among non-volatile organic acids
- OPTIMIZING THE VANILLIN-ACID SULFURIC METHOD TO TOTAL SAPONIN CONTENT IN LEAVES OF YERBA MATE CLONES
- Quadratic associations between cardiovascular stress reactivity and development of cool and hot executive functions in adolescents
- A Hydrogen Evolution Catalyst [Co2O2] Metallacycle Enables Regioselective Allene C(sp2)-H Functionalization
- Extract of Silphium perfoliatum L. improve lipid accumulation in NAFLD mice by regulating AMPK/FXR signaling pathway
- Differentiating the Yield of Chemical Reactions Using Parameters in First-Order Kinetic Equations to Identify Elementary Steps That Control the Reactivity from Complicated Reaction Path Networks
- Simultaneous quantification of 2-aminothiazoline-4-carboxylic acid and 2-aminothiazoline-4-oxoaminoethanoic acid utilizing chemical derivatization followed by liquid chromatography-tandem mass spectrometry
- Social Reactions to Disclosures of Multiple-Perpetrator Sexual Assault: Do Number of Offenders Matter?
- Promotion of Water as Solvent in Amination of 4-Chloropyrrolopyrimidines and Related Heterocycles under Acidic Conditions
- Single-step precision programming of decoupled multiresponsive soft millirobots
- Neurodevelopmental functions of CHD8: new insights and questions
- Supporting psychosis research, implementation, and training through an academic intermediary-purveyor organization
- Mitochondrial and Cellular Function in Fibroblasts, Induced Neurons, and Astrocytes Derived from Case Study Patients: Insights into Major Depression as a Mitochondria-Associated Disease
- Lactate/Hydroxycarboxylic Acid Receptor 1 in Alzheimer's Disease: Mechanisms and Therapeutic Implications-Exercise Perspective
- The levels of IL1RN is a factor influencing the onset of rheumatoid arthritis in non-alcoholic fatty liver disease
- Research progress on antibacterial applications of metal-organic frameworks and their biomacromolecule composites
- SEPN1-related myopathy depends on the oxidoreductase ERO1A and is druggable with the chemical chaperone TUDCA
- Weighing the role of social cognition and executive functioning in pragmatics in the schizophrenia spectrum: A systematic review and meta-analysis
- Understanding the role of ursodeoxycholic acid and gut microbiome in non-alcoholic fatty liver disease: current evidence and perspectives
- Functions and mechanisms of adenosine and its receptors in sleep regulation
- Extracts of tropical green seaweed Caulerpa lentillifera reduce hepatic lipid accumulation by modulating lipid metabolism molecules in HepG2 cells
- Specific association between retinal neural layer thinning and neurological soft signs in schizophrenia
- Electrophysiological Phenotypes of Hippocampal Synaptic and Network Functions in Cannabinoid Receptor 2 Knockout Mice
- Interaction between fatty acid oxidation and ethanol metabolism in liver
- Cysteine induces mitochondrial reductive stress in glioblastoma through hydrogen peroxide production
- Cysteine induces mitochondrial reductive stress in glioblastoma through hydrogen peroxide production
- Protein-Based Tools for Studying Neuromodulation
- Multimodal Neuroimaging of the Effect of Serotonergic Psychedelics on the Brain
- Association of the habitual dietary intake with the fatty liver index and effect modification by metabotypes in the population-based KORA-Fit study
- Chronic Ethanol Intake Impairs Niacin Nutritional Status in Mice
- Chronic Ethanol Intake Impairs Niacin Nutritional Status in Mice
- Transcranial random noise stimulation (tRNS) improves hot and cold executive functions in children with attention deficit-hyperactivity disorder (ADHD)
- SHMT2 reduces fatty liver but is necessary for liver inflammation and fibrosis in mice
- SHMT2 reduces fatty liver but is necessary for liver inflammation and fibrosis in mice
- Natural compounds mitigate mycotoxins-induced neurotoxicity by modulating oxidative tonus: in vitro and in vivo insights - a review
- Characteristics and Functions of Non-Suicidal Self-Injury That Inform Suicide Risk
- Exploring the immune-modulating properties of boswellic acid in experimental autoimmune encephalomyelitis
- Spexin and nesfatin-1-expressing neurons in the male human claustrum
- Evaluation of executive functions in children and adolescents with obesity
- Salvianolic acid A prevents UV-induced skin damage by inhibiting the cGAS-STING pathway
- Differentiating aliphatic and aromatic alcohols using triazine-based supramolecular organogelators: end group-specific selective gelation with chain length of alcohols
- The perception of Mandarin speech conveying communicative functions in Chinese heroin addicts
- TREX tetramer disruption alters RNA processing necessary for corticogenesis in THOC6 Intellectual Disability Syndrome
- Green synthesis of carbon nanotubes functionalized with iron nanoparticles and coffee husk biomass for efficient removal of losartan and diclofenac: Adsorption kinetics and ANN modeling studies
- Evolution of neuropsychological and behavioral profile in a cohort of pediatric patients with Becker muscular dystrophy in a longitudinal study
- Molecular-level insights into the temperature-dependent formation dynamics and mechanism of water-soluble dissolved organic carbon derived from biomass pyrolysis smoke
- Paroxysmal dystonia results from the loss of RIM4 in Purkinje cells
- Magnetization Vector Rotation Reservoir Computing Operated by Redox Mechanism
- Gypenoside XIII regulates lipid metabolism in HepG2 hepatocytes and ameliorates nonalcoholic steatohepatitis in mice
- Diffusion-weighted imaging does not seem to be a predictor of consistency in pituitary adenomas
- Paired electrocatalysis unlocks cross-dehydrogenative coupling of C(sp3)-H bonds using a pentacoordinated cobalt-salen catalyst
- Mechanisms of biased agonism by Gαi/o-biased stapled peptide agonists of the relaxin-3 receptor
- Serum Galectin-1, Galectin-9, and YKL-40 levels in bipolar disorder and their relationship with cognitive functions
- Limb-Clasping Response in NMDA Receptor Palmitoylation-Deficient Mice
- Likelihood ratio combination of multiple biomarkers via smoothing spline estimated densities
- CSF1R-mediated myeloid cell depletion shifts the ratio of motor cortical excitatory to inhibitory neurons in a multiple system atrophy model
- Effects of Ferulic Acid on Cognitive Function: A Systematic Review
- Skin Innervation
- Gamma-aminobutyric acid as a potential postbiotic mediator in the gut-brain axis
- Development of Pyridothiophene Compounds for PET Imaging of α-Synuclein
- Evolution of the nervous system by acquisition of retrovirus-derived genes in mammals
- Perceived functions and importance of digital media use and adolescent depression and suicidal ideation
- Protocol for gene knockdown using siRNA in primary cultured neonatal murine microglia
Evidence Blueprint
Supported Noble Metal Catalysts and Adsorbents with Soft Lewis Acid Functions
☊ AI-Driven Related Evidence Nodes
(recent articles with at least 5 words in title)
Save Evidence Blueprint
Save as PDF
Supported Noble Metal Catalysts and Adsorbents with Soft Lewis Acid Functions
🌐 365 Days
VR Related Evidence Matrix
- Ga-Pt supported catalytically active liquid metal solutions (SCALMS) prepared by ultrasonication - influence of synthesis conditions on n-heptane dehydrogenation performance
- A novel activation function based on DNA enzyme-free hybridization reaction and its implementation on nonlinear molecular learning systems
- Defluorination of perfluorooctanoic acid and perfluorooctane sulfonic acid by heterogeneous catalytic system of Fe-Al2O3/O3: Synergistic oxidation effects and defluorination mechanism
- Succinic acid production by wine yeasts and the influence of GABA and glutamic acid
- Exploration of carbonyl compounds in red-fleshed kiwifruit wine and perceptual interactions among non-volatile organic acids
- Humanized mouse liver reveals endothelial control of essential hepatic metabolic functions
- OPTIMIZING THE VANILLIN-ACID SULFURIC METHOD TO TOTAL SAPONIN CONTENT IN LEAVES OF YERBA MATE CLONES
- Heterogeneous H2O2-based selective oxidations over zirconium tungstate α-ZrW2O8
- ADME properties of CHF6366, a novel bi-functional M3-Muscarinic receptor antagonist and ß-2 adrenoceptor agonist (MABA) radiolabeled at both functional moieties
- Additive-free selective oxidation of aromatic alcohols with molecular oxygen catalyzed by a mixed-valence polyoxovanadate-based metal-organic framework
- Untargeted LC-QTOF-MS/MS-based metabolomics of spent coffee grounds alcoholic beverages fermented with Lachancea thermotolerans and Lactiplantibacillus plantarum
- Quadratic associations between cardiovascular stress reactivity and development of cool and hot executive functions in adolescents
- Caffeoylquinic acids protect against alcoholic liver injury and rare C10 acetylenic acids from Erigeron breviscapus
- Molecular docking and dynamics simulations revealed the potential inhibitory activity of honey-iQfood ingredients against GSK-3β and CDK5 protein targets for brain health
- Cognitive Functions in Obsessive Compulsive Disorder and Its Relationship with Oxidative Metabolism
- A Hydrogen Evolution Catalyst [Co2O2] Metallacycle Enables Regioselective Allene C(sp2)-H Functionalization
- Extract of Silphium perfoliatum L. improve lipid accumulation in NAFLD mice by regulating AMPK/FXR signaling pathway
- Evaluation of the differences between low-salt solid-state fermented soy sauce and high-salt diluted-state fermented soy sauce in China: From taste-active compounds and aroma-active compounds to sensory characteristics
- 11C-Fixation Techniques
- Study on the relationship between flavor components and quality of ice wine during freezing and brewing of 'beibinghong' grapes
- Dissecting the role of cadmium, lead, arsenic, and mercury in non-alcoholic fatty liver disease and non-alcoholic steatohepatitis
- Differentiating the Yield of Chemical Reactions Using Parameters in First-Order Kinetic Equations to Identify Elementary Steps That Control the Reactivity from Complicated Reaction Path Networks
- Phosphonium based anion exchange resin for enrichment of phenolic acids
- Oxford University Chancellor appointed Knight Companion of the Most Noble Order of the Garter
- Identification of Brain-Penetrant ATP-Competitive mTOR Inhibitors for CNS Syndromes
- Dual Piperidine-Based Histamine H3 and Sigma-1 Receptor Ligands in the Treatment of Nociceptive and Neuropathic Pain
- Simultaneous quantification of 2-aminothiazoline-4-carboxylic acid and 2-aminothiazoline-4-oxoaminoethanoic acid utilizing chemical derivatization followed by liquid chromatography-tandem mass spectrometry
- Possible roles of deep cortical neurons and oligodendrocytes in the neural basis of human sociality
- Optimization of chromatographic buffer conditions for the simultaneous analysis of phosphatidylinositol and phosphatidylinositol phosphate species in canola
- Robust and efficient transfer hydrogenation of carbonyl compounds catalyzed by NN-Mn(I) complexes
- Dynamic genome-scale modeling of Saccharomyces cerevisiae unravels mechanisms for ester formation during alcoholic fermentation
- Folate and Its Significance in Depressive Disorders and Suicidality: A Comprehensive Narrative Review
- The effects of abnormal visual experience on neurodevelopmental disorders
- Reactive oxygen species (ROS)-mediated oxidative stress in chronic liver diseases and its mitigation by medicinal plants
- Can Electronic Nose Replace Human Nose?-An Investigation of E-Nose Sensor Responses to Volatile Compounds in Alcoholic Beverages
- Do stigma and efficacy mediate the association between training and suicide prevention behavior among Army noncommissioned officers?
- Organic Selenium induces ferroptosis in pancreatic cancer cells
- In Vivo Intracerebral Administration of α-Ketoisocaproic Acid to Neonate Rats Disrupts Brain Redox Homeostasis and Promotes Neuronal Death, Glial Reactivity, and Myelination Injury
- Social Reactions to Disclosures of Multiple-Perpetrator Sexual Assault: Do Number of Offenders Matter?
- Based on network pharmacology and experiments to explore the underlying mechanism of Mahonia bealei (Fortune) Carrière for treating alcoholic hepatocellular carcinoma
- The regulation of amino acid metabolism in tumor cell death: from the perspective of physiological functions
- Circular RNAs in non-alcoholic fatty liver disease: Functions and clinical significance
- Using Pivotal Response Treatment to Improve Language Functions of Autistic Children in Special Schools: A Randomized Controlled Trial
- Promotion of Water as Solvent in Amination of 4-Chloropyrrolopyrimidines and Related Heterocycles under Acidic Conditions
- Computational Studies and Antimicrobial Activity of 1-(benzo[d]oxazol-2-yl)-3,5-Diphenylformazan Derivatives
- Enzymatic colorimetric method for turn-on determination of l-lactic acid through indicator displacement assay
- 3-Pyrrolyl BODIPY Based Schiff Base Fluorophores: Selective Chemodosimetric and Optical Sensor for Diethyl Chlorophosphate
- Potassium channels in behavioral brain disorders. Molecular mechanisms and therapeutic potential: a narrative review
- Calcium signalling in hepatic metabolism: Health and diseases
- The intra-individual reliability of 1 H-MRS measurement in the anterior cingulate cortex across 1 year
- Saffron and crocin ameliorate prenatal valproic acid-induced autistic-like behaviors and brain oxidative stress in the male offspring rats
- Analytical refractory period distribution for a class of time-variant biochemical systems with second-order reactions
- 9-POHSA prevents NF-kB activation and ameliorates LPS-induced inflammation in rat hepatocytes
- Analysis of Volatile and Nonvolatile Constituents in Gin by Direct-Infusion Ultrahigh-Resolution ESI/APPI FT-ICR Mass Spectrometry
- Design of Tetrazolium Cations for the Release of Antiproliferative Formazan Chelators in Mammalian Cells
- Tripeptides conjugated with thiosemicarbazones: new inhibitors of tyrosinase for cosmeceutical use
- Role of the GRP/GRPR System in Regulating Brain Functions
- Epigenetic Regulation of Hepatic Lipid Metabolism by DNA Methylation
- QTL mapping reveals novel genes and mechanisms underlying variations in H2S production during alcoholic fermentation in Saccharomyces cerevisiae
- Amyloid Targeting Red Emitting AIE Dots for Diagnostic and Therapeutic Application against Alzheimer's Disease
- Neuroprotective Efficacy of Fisetin Against VPA-Induced Autistic Neurobehavioral Alterations by Targeting Dysregulated Redox Homeostasis
- Association between mental health, psychological characteristics, and motivational functions of volunteerism among Polish and Ukrainian volunteers during the Russo-Ukrainian War
- Identification of novel dithiocarbamate-copper complexes targeting p97/NPL4 pathway in cancer cells
- Single-step precision programming of decoupled multiresponsive soft millirobots